{"id":33,"date":"2018-05-23T19:26:54","date_gmt":"2018-05-23T19:26:54","guid":{"rendered":"http:\/\/wpdev.acsu.buffalo.edu\/dclubchem\/?page_id=33"},"modified":"2026-08-07T20:38:30","modified_gmt":"2026-08-07T20:38:30","slug":"publications","status":"publish","type":"page","link":"https:\/\/ubwp.buffalo.edu\/lacylab\/publications\/","title":{"rendered":"Publications"},"content":{"rendered":"<h3 style=\"text-align: center\"><strong><em>Selected Publications<\/em><\/strong><\/h3>\n<div class=\"pubs-selected\"><a href=\"https:\/\/doi.org\/10.1021\/jacs.2c08509\"><img decoding=\"async\" src=\"https:\/\/ubwp.buffalo.edu\/lacylab\/wp-content\/uploads\/sites\/96\/2022\/11\/cropped-trichloridobistriphenylphosphineoxidemanganeseIII.png\" alt=\"Bench-stable manganese(III) chloride complex\" \/>Bench-stable Mn(III)Cl<sub>3<\/sub><em>JACS 2022<\/em><\/a><a href=\"https:\/\/doi.org\/10.1021\/jacs.3c03651\"><img decoding=\"async\" src=\"https:\/\/ubwp.buffalo.edu\/lacylab\/wp-content\/uploads\/sites\/96\/2022\/09\/A1-CD-vial.png\" alt=\"Manganese chloride bond dissociation free energy measurement\" \/>The Cl-atom in a bottle<em>JACS 2023<\/em><\/a><a href=\"https:\/\/doi.org\/10.1021\/jacs.4c03411\"><img decoding=\"async\" src=\"https:\/\/ubwp.buffalo.edu\/lacylab\/wp-content\/uploads\/sites\/96\/2024\/04\/images_large_ja4c03411_0009.jpeg\" alt=\"Manganese(III) nitrate complex and cyclic voltammogram\" \/>Bench-stable powerful oxidants<em>JACS 2024<\/em><\/a><a href=\"https:\/\/doi.org\/10.1021\/acs.inorgchem.4c01820\"><img decoding=\"async\" src=\"https:\/\/ubwp.buffalo.edu\/lacylab\/wp-content\/uploads\/sites\/96\/2026\/08\/SP1-scaled-e1786134322419.png\" alt=\"MnX3 phosphine complexes\" \/>MnX<sub>3<\/sub> with phosphine ligands<em>Inorg. Chem. 2024<\/em><\/a><\/div>\n<p style=\"text-align: center\"><a href=\"https:\/\/scholar.google.com\/citations?user=3tFEhigAAAAJ&amp;hl=en\">Link to Google Scholar<\/a><br \/>\n(* = corresponding author;\u00a0<sup>\u2021<\/sup> = undergraduate authors;\u00a0<em><sup>\u00a7<\/sup><\/em> = equally contributing)<\/p>\n<h3 style=\"text-align: center\"><strong><em>Preprints\u00a0<\/em><\/strong><\/h3>\n<p><strong>52<\/strong>. Saju, A.; Kumari, A.; Crawley, M. R.; Lacy,* D. C. Acid-triggered access to reactive {Mn(III)X} intermediates. Part 1. <a href=\"https:\/\/doi.org\/10.26434\/chemrxiv.15007078\/v1\">Mn(III) triflate complexes for alkene dihalogenation and benzylic C\u2013H halogenation using mineral acid (HCl, HBr, and HNO<span data-olk-copy-source=\"MessageBody\"><sub>3<\/sub><\/span>)<\/a>. <em>ChemRxiv <\/em><strong>2026<\/strong>, DOI: 10.26434\/chemrxiv.15007078\/v1<\/p>\n<p><strong>51<\/strong>.\u00a0Kumari, A.; Saju, A.; Crawley, M. R.; Burch, J. E.; Gupta, R.; Friedman, A. E.; Lacy,* D. C. Acid-triggered access to reactive {Mn(III)X} intermediates. Part 2. <a href=\"https:\/\/doi.org\/10.26434\/chemrxiv.15007077\/v1\">Freely soluble forms of manganese(III) acetate<\/a>. <em>ChemRxiv <\/em><strong>2026<\/strong>, DOI: 10.26434\/chemrxiv.15007077\/v1<\/p>\n<h3 style=\"text-align: center\"><strong><em>Published Manuscripts<\/em><\/strong><\/h3>\n<p><strong>50<\/strong>.\u00a0Abhyankar,* P. C.; Siriwardana, B. S.; Tarbox, R. P.; Martinez-Rivera,<sup>\u2021<\/sup> E. Crawley, M. R., Cook,* T. R.; Velarde,* L.; Lacy,* D. C. <a href=\"https:\/\/doi.org\/10.1021\/acs.organomet.5c00514\">Dinuclear Mn complexes featuring formal metal-metal double bonds<\/a>. <em>Organometallics<\/em> <strong>2026<\/strong>, 45, 1221-1231.<\/p>\n<p style=\"text-align: center\">\n<p><strong>49<\/strong>. Saju, A.; Le Magueres, P.; Del Campo, M.; Crawley, M. R.;* Lacy,*\u00a0D. C.\u00a0<a href=\"https:\/\/www.tandfonline.com\/doi\/full\/10.1080\/00958972.2026.2709489\"><span data-olk-copy-source=\"MessageBody\">Synthesis and MicroED Characterization of [Mn(III)Cl<sub>2<\/sub>(dppmO)<sub>2<\/sub>]<sub>2<\/sub>[Mn(III)Cl<sub>5<\/sub>] (dppmO = methylene-bis(diphenylphosphine oxide)<\/span><\/a>. <em>J. Coord. Chem. <\/em><strong>2026<\/strong>, DOI: <span data-olk-copy-source=\"MessageBody\">10.1080\/00958972.2026.2709489.<\/span><\/p>\n<p><strong>48<\/strong>. Saju, A.; Crawley, M. R.; Lacy,*\u00a0D. C. <a href=\"https:\/\/doi.org\/10.1080\/00958972.2026.2654808\">Synthesis and characterization of (TAS)<sub>2<\/sub>[Mn(III)Cl<sub>3<\/sub>F<sub>2<\/sub>] (TAS = tris(dimethylamino)sulfonium)<\/a>. <em>J. Coord. Chem. <\/em><strong>2026<\/strong>, 79, 1002-1007.<\/p>\n<p><strong>47<\/strong>. Roche-Rivera, Z.; Abhyankar, P. C.; Crawley, M. R.; Lacy,* D. C. <a href=\"https:\/\/doi.org\/10.1080\/00958972.2025.2453066\">Synthesis of Ph<sub>3<\/sub>PO-stabilized Mo(V) and (VI) imido complexes<\/a>. <em>J. Coord. Chem. <\/em><strong>2025<\/strong>, 78, 347-355.<\/p>\n<p><strong>46<\/strong>. Saju, A.; Crawley, M. R.; MacMillan, S. N.; Le Magueres, P.; Del Campo, M.; Lacy.* D. C. <a href=\"https:\/\/doi.org\/10.3390\/molecules29194670\"><em>N<\/em>-oxide coordination to Mn(III) chloride<\/a>. <em>Molecules<\/em> <strong>2024<\/strong>,\u00a0 <em>29<\/em>(19), 4670.<\/p>\n<p><strong>45<\/strong>. Paul, S.; Saju, A.; Cohen,<sup>\u2021<\/sup> C.; Crawley, M. R.; MacMillan, S. N.; Lacy.* D. C. <a href=\"https:\/\/doi.org\/10.1021\/acs.inorgchem.4c01820\">Synthesis of MnX<sub>3<\/sub> (X = Cl, Br, I) compounds with phosphine (R<sub>3<\/sub>P) ligands<\/a>. <em>Inorg. Chem. <\/em><strong>2024<\/strong>, <em>63<\/em>, 15791-15803.<\/p>\n<p><strong>44<\/strong>. Saju, A.; Crawley, M. R.; MacMillan, S. N.; Lacy.* D. C. <a href=\"https:\/\/doi.org\/10.1021\/jacs.4c03411\">Manganese(III) nitrate complexes as bench-stable powerful oxidants<\/a>. <em>J. Am. Chem. Soc.<\/em> <strong>2024<\/strong>,\u00a0<em>146<\/em>, <span class=\"cit-pageRange\">11616\u201311621<\/span>.<\/p>\n<p><strong>43<\/strong>. Lacy,* D. C.; Heppner,* D. E.; Buckley,<sup>\u00a7 <\/sup>B.; Griffiths,<sup>\u00a7<\/sup> J.; Gunasekera,<sup>\u00a7<\/sup> P. S.; Patel,<sup>\u00a7<\/sup> P.; Roche-Rivera,<sup>\u00a7\u2021<\/sup> Z.; Coppola,<sup>\u2021 <\/sup>K.; Dempsey,<sup>\u2021<\/sup> K.; Pillai,<sup>\u2021<\/sup> S.; Renzoni<sup>\u2021<\/sup> B. <a href=\"https:\/\/doi.org\/10.1016\/j.poly.2024.116859\">Twelve CO molecules for the price of one. A simple water-soluble CORM, [Mn(CO)<sub>3<\/sub>(\u00b5-OH)]<sub>4<\/sub>.<\/a> <em>Polyhedron<\/em> <strong>2024<\/strong>,\u00a0<em>251<\/em>, 116859. <em><br \/>\n<\/em><\/p>\n<p><strong>42<\/strong>. Gunasekera, P. S.; Paul, S.; MacMillan, S. N.; Lacy,* D. C. <a href=\"https:\/\/doi.org\/10.1002\/ejic.202300757\">Synthesis and characterization of dearomatized pyridine-derived alkyl-amido-<em>tert<\/em>-butylphosphine iron(II) complexes<\/a>. <em>Eur. J. Inorg. Chem. <\/em><strong>2024<\/strong>,\u00a0<em>27<\/em>, e202300757.<\/p>\n<p><strong>41<\/strong>. Saju,<em><sup>\u00a7<\/sup><\/em> A.; Gunasekera,<em><sup>\u00a7<\/sup><\/em> P. S.; Morgante, P.; MacMillan, S. N.; Autschbach,* J.; Lacy,* D. C. <a href=\"https:\/\/doi.org\/10.1021\/jacs.3c03651\" target=\"_blank\" rel=\"noopener\">Experimental and Computational Determination of a M\u2013Cl Homolytic Bond Dissociation Free Energy: Mn(III)Cl Mediated C\u2013H Cleavage and Chlorination<\/a>. <em>J. Am. Chem. Soc.<\/em> <strong>2023<\/strong>,\u00a0<em>145<\/em>, <span class=\"cit-pageRange\">13384\u201313391<\/span>. DOI: 10.1021\/jacs.3c03651.<\/p>\n<p><strong>40<\/strong>. Lacy,* D. C.; Abhyankar, P. C. <a href=\"https:\/\/doi.org\/10.1002\/chem.202300518\" target=\"_blank\" rel=\"noopener\">Dinuclear Mn(I) complexes with phosphido and hydrido bridges: synthesis, reactivity, and hydrogenative catalysis<\/a> <em>Chem. Eur. J. <\/em><strong>2023<\/strong>, e202300518.<\/p>\n<p><strong>39<\/strong>. Saju, A.; Griffiths, J. R.; MacMillan, S. N.; Lacy,* D. C. <a href=\"https:\/\/doi.org\/10.1021\/jacs.2c08509\">Synthesis of a bench-stable manganese(III) chloride compound: coordination chemistry and alkene dichlorination<\/a>\u00a0<em>J. Am. Chem. Soc.<\/em> <strong>2022<\/strong>, <em>144<\/em>, 16761.<\/p>\n<p><strong>38<\/strong>. Abhyankar, P. C.; MacMillan, S. N.; Lacy,* D. C. <a href=\"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/10.1002\/chem.202201766\" target=\"_blank\" rel=\"noopener\">Bench-stable dinuclear Mn(I) catalysts in E-selective alkyne semihydrogenation: a mechanistic investigation<\/a> <em>Chem., Eur. J. <\/em><strong>2022<\/strong><em>, 28, <\/em>e202201766.<\/p>\n<p><strong>37<\/strong>. Paul, S.; Morgante, P.; MacMillan, S. N.; Autschbach,* J.; Lacy,* D. C. <a href=\"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/10.1002\/chem.202201042\" target=\"_blank\" rel=\"noopener\"><span style=\"text-decoration: underline\">Hydrogenative catalysis with three-coordinate zinc complexes supported with PN ligands is enhanced compared to PNP analogs<\/span><\/a> <i>Chem., Eur. J. <\/i><strong>2022<\/strong>, <em>28<\/em>, e202201042.<\/p>\n<p><strong>36<\/strong>. Abhyankar, P. C.; MacMillan, S. N.; Lacy,* D. C. <a href=\"https:\/\/pubs.acs.org\/doi\/10.1021\/acs.organomet.1c00603\" target=\"_blank\" rel=\"noopener\"><span style=\"text-decoration: underline\">Activation of H<sub>2<\/sub> with dinuclear manganese(I)-phosphido complexes<\/span><\/a> <i>Organometallics <\/i><strong>2022<\/strong>,\u00a0<em>41<\/em>, 60-66.<\/p>\n<p><strong>35<\/strong>. Vigneswaran, V.; Abhyankar, P. C.; MacMillan, S. N.; Lacy,* D. C. <a href=\"https:\/\/pubs.acs.org\/doi\/10.1021\/acs.organomet.1c00606\" target=\"_blank\" rel=\"noopener\"><span style=\"text-decoration: underline\">H<sub>2<\/sub> activation across manganese(I)-C bonds: atypical metal-ligand cooperativity in the aromatization\/dearomatization paradigm<\/span><\/a> <i>Organometallics <\/i><strong>2022<\/strong><i>, 41<\/i>, 67-75.<\/p>\n<p><strong>34<\/strong>. Fanara,<em><sup>\u00a7<\/sup><\/em> P. M.; Vigneswaran,<em><sup>\u00a7<\/sup><\/em> V.; Gunasekera, P. S.; MacMillan, S. N.; Lacy,* D. C. <a href=\"https:\/\/pubs.acs.org\/doi\/10.1021\/acs.organomet.1c00648\" target=\"_blank\" rel=\"noopener\"><span style=\"text-decoration: underline\">Reversible photoisomerization in a Ru cis-dihydride catalyst accessed through atypical metal\u2013ligand cooperative H<sub>2<\/sub> activation: photoenhanced acceptorless alcohol dehydrogenation<\/span><\/a> \u00a0<i>Organometallics <\/i><strong>2022<\/strong><i>,\u00a0<\/i><em>41<\/em>, 93-98.<\/p>\n<p><strong>33<\/strong>. Lacy,* D. C.; Paul, S.; Vigneswaran, V.; Abhyankar, P. C. <a href=\"https:\/\/www.sciencedirect.com\/science\/article\/pii\/B9780128202067000603\" target=\"_blank\" rel=\"noopener\"><u>Carbonyl and Isocyanide Complexes of Manganese<\/u><\/a>, Chapter 6.06 <em>Comprehensive Organometallic Chemistry IV;<\/em> Elsevier <strong>2021<\/strong>, <em>6<\/em>, 449-552.<\/p>\n<p><strong>32<\/strong>. Gunasekera, P. S.; MacMillan, S. N.; Lacy,* D. C. <a href=\"https:\/\/www.tandfonline.com\/doi\/abs\/10.1080\/00958972.2021.1878353?journalCode=gcoo20\"><span style=\"text-decoration: underline\">Synthesis and coordination of a <em>tert<\/em>-butyl functionalized facially coordinating 2-histidine 1-carboxylate model ligand<\/span><\/a>.<em>\u00a0J. Coord. Chem<\/em>.\u00a0<strong>2021<\/strong>,\u00a0<em>74<\/em>, 315-320.<\/p>\n<p><strong>31<\/strong>. Gunasekera, P. S.; Abhyankar, P. C.; MacMillan, S. N.; Lacy,* D. C. <a href=\"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/10.1002\/ejic.202000984\"><span style=\"text-decoration: underline\">A facially coordinating tris-benzimidazole ligand for nonheme iron enzyme models<\/span><\/a>. <em>Eur. J. Inorg. Chem. <\/em><strong>2021<\/strong>, <em>2021<\/em>, 654-657.<\/p>\n<p><strong>30<\/strong>. Fanara, P. M.; MacMillan, S. N.;\u00a0 Lacy,* D. C. <a href=\"https:\/\/pubs.acs.org\/doi\/full\/10.1021\/acs.organomet.0c00327\"><u>Planar-locked Ru-PNN catalysts in 1-phenylethanol dehydrogenation<\/u><\/a>. \u00a0<em>Organometallics<\/em>, <strong>2020<\/strong>, <em>39<\/em>, 3628-3644.<\/p>\n<p><strong>29<\/strong>. Kadassery, K. J.; Crawley, M. R.; MacMillan, S. N.; Lacy,* D. C. <a href=\"https:\/\/pubs.rsc.org\/en\/content\/articlelanding\/2020\/DT\/D0DT00973C#!divAbstract\" target=\"_blank\" rel=\"noopener noreferrer\">A Hemilabile Manganese(I)-Phenol Complex and its Coordination Induced O\u2013H Bond Weakening<\/a>. <em>Dalton Trans.<\/em>\u00a0<b>2020<\/b><i>, <\/i><em>49<\/em>, 16217-16255<span class=\"cit-pageRange\">.<\/span><\/p>\n<p><strong>28<\/strong>. Vigneswaran, V.; MacMillan, S. N.; Lacy,* D. C. <a href=\"https:\/\/pubs.acs.org\/doi\/abs\/10.1021\/acs.organomet.9b00692\" target=\"_blank\" rel=\"noopener noreferrer\">Beta-Amino Phosphine Mn Catalysts for 1,4-Transfer Hydrogenation of Chalcones and Allylic Alcohol Isomerization<\/a>.\u00a0<em>Organometallics<\/em>\u00a0<b>2019<\/b><i>, <span class=\"cit-volume\">38<\/span><span class=\"cit-issue\">, <\/span><\/i><span class=\"cit-pageRange\">4387-4391.<\/span><\/p>\n<p><strong>27<\/strong>. Lacy,* D. C. <a href=\"https:\/\/pubs.rsc.org\/en\/content\/articlelanding\/2019\/qi\/c9qi00828d#!divAbstract\">Applications of the Marcus Cross Relation to Inner Sphere O<sub>2<\/sub> Reduction: Implications in Small Molecule Activation<\/a>. <em>Inorg. Chem. Front.\u00a0 <\/em><strong>2019<\/strong>, <em>6<\/em>, 2396-2403.<\/p>\n<p><strong>26<\/strong>. Kadassery, K. J.;\u00a0MacMillan, S. N.; Lacy,* D. C. <a href=\"http:\/\/dx.doi.org\/10.1021\/acs.inorgchem.9b00941\"><span style=\"text-decoration: underline\">Resurgence of Organomanganese(I) Chemistry. Bidentate Phosphine-Phenol(ate) Mn(I) Complexes<\/span><\/a>. <em>Inorg. Chem.\u00a0<\/em><strong>2019<\/strong>, <em>58<\/em>, <span class=\"pageRange\">10527-10535<\/span>.<\/p>\n<p><strong>25<\/strong>. Crawley, M. R.; Kadassery, K. J.; Oldacre, A. N.; Freidman, A. E.; Lacy,* D. C.; Cook,* T. R. <a href=\"https:\/\/pubs.acs.org\/doi\/10.1021\/acs.organomet.9b00138\"><u>Rhenium(I) phosphazane complexes for electrocatalytic CO<sub>2<\/sub> reduction<\/u><\/a>. <em>Organometallics.<\/em>\u00a0\u00a0<strong>2019<\/strong>,\u00a0<span class=\"citation_volume\">38<\/span>, 1664\u20131676.<\/p>\n<p><strong>24<\/strong>. Kadassery,<em><sup>\u00a7<\/sup><\/em> K. J.; Sethi,<em><sup>\u00a7\u00a0<\/sup><\/em>K.; Fanara, P. M.; Lacy,* D. C. <a href=\"https:\/\/pubs.acs.org\/doi\/10.1021\/acs.inorgchem.9b00322\">CO-photolysis-induced H-atom transfer from Mn(I)O\u2013H bonds<\/a><em>.\u00a0<\/em>\u00a0<em>Inorg. Chem<\/em>.\u00a0<strong>2019,\u00a0<\/strong><em><span class=\"citation_volume\">58<\/span><\/em>, 4679\u20134685.<\/p>\n<p><strong>23<\/strong>. Kadassery, K. J.; Lacy,* D. C. <a href=\"https:\/\/pubs.rsc.org\/en\/content\/articlelanding\/2019\/dt\/c9dt00529c#!divAbstract\">Pentacarbonylmethylmanganese(I) as a synthon for Mn(I) pincer catalysts<\/a><em>.<\/em>\u00a0\u00a0<em>Dalton Trans<\/em>.\u00a0<strong>2019<\/strong>,\u00a0<em>48<\/em>, 4467 &#8211; 4470.<\/p>\n<p><strong>22<\/strong>. Cannella, A. F.; Surendhran,<sup>\u2021<\/sup> R.; MacMillan, S. N.; Gupta, R.; Lacy,* D. C. <a href=\"https:\/\/www.tandfonline.com\/doi\/full\/10.1080\/00958972.2019.1601714\"><span style=\"text-decoration: underline\">Electronically varied manganese tris-arylacetamide tripodal complexes<\/span><\/a>. <em>J. Coord. Chem<\/em>.\u00a0<strong>2019<\/strong>, <em>72<\/em>,\u00a01287-1297. Article in &#8220;Emerging Leader Issue&#8221;<\/p>\n<p><strong>21<\/strong>. Guan, Y.-S.; Zhong, G.; Hu, Y.; Cannella, A. F.; Li, C.; Lee, N.; Jia,* Q.; Lacy,* D. C.; Ren,* S. <a href=\"https:\/\/onlinelibrary.wiley.com\/doi\/abs\/10.1002\/adma.201806263\" target=\"_blank\" rel=\"noopener noreferrer\"><u>Magnetoelectric radical hydrocarbons<\/u><\/a>. <em>Adv. Mater.<\/em>\u00a0<strong>2018<\/strong>,\u00a0<em>31<\/em><span class=\"current-selection\">, 1806263.<\/span><\/p>\n<p><strong>20<\/strong>. Andrews, J. L.; Cho, J.; Wangoh, L.; Suwandaratne, N.; Sheng, A.; Chauhan S.; Nieto, K.; Mohr, A.; Kadassery, K. J.; Popeil, M. R.; Thakur, P. K.; Sfeir, M.; Lacy, D. C.; Lee, T.-L.; Zhang, P.; Watson,* D. F.; Piper,* L. F. J.; Banerjee,* S.; <a href=\"https:\/\/pubs.acs.org\/doi\/10.1021\/jacs.8b09924\"><u>Hole extraction by design in photocatalytic architectures interfacing CdSe quantum dots with topochemically-stabilized tin vanadium oxide<\/u><\/a>. <em>J. Am. Chem. Soc. <\/em><strong>2018<\/strong>,\u00a0<em>140<\/em>, 17163-17174.<\/p>\n<p><strong>19<\/strong>. Kadassery, K. J.; MacMillan, S. N.; Lacy,* D. C. <a href=\"http:\/\/pubs.rsc.org\/en\/content\/articlelanding\/2014\/DT\/C8DT02933D#!divAbstract\" target=\"_blank\" rel=\"noopener noreferrer\">Bisphosphine phenol and phenolate complexes of Mn(I): Manganese(I) catalyzed Tishchenko reaction<\/a>\u00a0<em>Dalton. Trans.\u00a0<\/em><strong>2018<\/strong>, <em>47<\/em>,\u00a012652-12655.<\/p>\n<p><strong>18<\/strong>. Surendhran,<sup>\u2021<\/sup> R.;\u00a0D\u2019Arpino,<sup>\u2021<\/sup> A. A.; Sciscent,<sup>\u2021<\/sup>\u00a0B. Y.;\u00a0Cannella, A. F.; Friedman, A. E.; MacMillan, S. N.; Rupal, G.; Lacy,* D. C.\u00a0<a href=\"http:\/\/pubs.rsc.org\/en\/content\/articlelanding\/2014\/SC\/C8SC01621F#!divAbstract\" target=\"_blank\" rel=\"noopener noreferrer\"><u>Deciphering the Mechanism of O<sub>2<\/sub> Reduction with Electronically Tunable Non-Heme Iron Enzyme Model Complexes<\/u><\/a> <em>Chem. Sci.<\/em> <strong>2018<\/strong>,<b><i> <\/i><\/b><em>9<\/em>, 5773-5780.<\/p>\n<p><strong>17<\/strong>. Cannella, A. F.;\u00a0Dey, S. K. MacMillan, S. N.; Lacy,* D. C.\u00a0<a href=\"http:\/\/pubs.rsc.org\/en\/Content\/ArticleLanding\/2018\/DT\/C8DT00537K#!divAbstract\" target=\"_blank\" rel=\"noopener noreferrer\">Structural Diversity in Pyridine and Polypyridine Adducts of Ring Slipped Manganocene: Correlating Ligand Steric Bulk with Quantified Deviation from Ideal Hapticity<\/a>.\u00a0<em>Dalton Trans.<\/em>\u00a0<strong>2018<\/strong>,<strong>\u00a0<\/strong><em>47<\/em>, 5171-5180. Cover article for 2018 issue 15.<\/p>\n<p><strong>16<\/strong>. Kadassery, K. J.; Dey, S. K.; Cannella, A. F.; Surendhran,<sup>\u2021<\/sup> R. Lacy,* D. C. <a href=\"https:\/\/pubs.acs.org\/doi\/abs\/10.1021\/acs.inorgchem.7b01483\" target=\"_blank\" rel=\"noopener noreferrer\">Photochemical Water Splitting with Organomanganese Complexes<\/a><em>.<\/em>\u00a0<em>Inorg. Chem.<\/em><strong><span class=\"citation_year\">2017<\/span><\/strong>,\u00a0<em><span class=\"citation_volume\">56<\/span><\/em>\u00a0(16), 9954\u20139965.<\/p>\n<p><strong>15<\/strong>. Kadassery, K. J.; Dey, S. K.; Friedman, A. E.; Lacy,* D. C. <a href=\"https:\/\/pubs.acs.org\/doi\/10.1021\/acs.inorgchem.7b01438\" target=\"_blank\" rel=\"noopener noreferrer\">Exploring the Role of Carbonate in the Formation of an Organomanganese Tetramer<\/a>. <em>Inorg. Chem. <\/em><strong>2017<\/strong>,\u00a0<em><span class=\"citation_volume\">56<\/span><\/em>\u00a0(15), 8748\u20138751.<\/p>\n<h3 style=\"text-align: left\">Publications from graduate and postdoctoral studies<\/h3>\n<p><strong>14.<\/strong> Hill, E. A.; Weitz, A. C.; Onderko, E.; Romero-Rivera, A.; Guo,* Y.; Swart,* M.; Bominaar,* E. L.; Green,* M. T.; Hendrich,* M. P.; Lacy,* D. C.; Borovik,* A. S.; <span style=\"text-decoration: underline\"><a href=\"https:\/\/pubs.acs.org\/doi\/abs\/10.1021\/jacs.6b07633\" target=\"_blank\" rel=\"noopener noreferrer\">Reactivity of an Fe(IV)-Oxo Complex with Protons and Oxidants<\/a><\/span>.\u00a0<em>J. Am. Chem. Soc. <\/em>(2016),\u00a0<em>138<\/em>, 13143-13146.<\/p>\n<p><strong>13. <\/strong><em>Book Chapter <\/em>Cook, S. A.; Lacy, D. C.; Borovik, A. S.; <a href=\"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/9781118898277.ch10\" target=\"_blank\" rel=\"noopener noreferrer\">Terminal Metal-Oxo Species with Unusual Spin States<\/a>. <em>Book Chapter in Spin States in Biochemistry and Inorganic Chemistry: Influence on Structure and Reactivity<\/em> Swart, M. and Costas M.; John Wiley &amp; Sons, Ltd., 2016<\/p>\n<p><strong>12.<\/strong> Lacy, David C.; Roberts,<sup>\u2021<\/sup> G. M.;\u00a0Peters,* J. C.; <a href=\"https:\/\/pubs.acs.org\/doi\/abs\/10.1021\/jacs.5b01838\" target=\"_blank\" rel=\"noopener noreferrer\"><span style=\"text-decoration: underline\">The Cobalt Hydride that Never Was: Revisiting Schrauzer\u2019s \u201cHydridocobaloxime.\u201d<\/span><\/a> <em>J.<\/em><em>\u00a0Am. Chem. Soc. <\/em>(2015) <em>137<\/em>, 4860-4684.<\/p>\n<p><strong>11.<\/strong> Sieh,<em><sup>\u00a7<\/sup><\/em> D.; Lacy,<em><sup>\u00a7<\/sup><\/em> D. C. ; Peters,* J. C.; Kubiak,* C. P.; <a href=\"https:\/\/onlinelibrary.wiley.com\/doi\/abs\/10.1002\/chem.201500463\" target=\"_blank\" rel=\"noopener noreferrer\"><span style=\"text-decoration: underline\">Reduction of CO<sub>2<\/sub> by pyridine monoamine molybdenum carbonyl complexes: Cooperative Metal-Ligand Binding of CO<sub>2<\/sub><\/span><\/a>. <em>Chem., Eur. J<\/em>. (2015) <em>21<\/em>, 8497-8503. \u00a7 = Equally contributing<\/p>\n<p><strong>10.<\/strong> Zhang, M.; El-Roz, M.; Mendoza-Cortez, J. L.; Lacy, D. C.; Peters,* J. C.; Head-Gordon,* M.; Frei,* H.; <a href=\"https:\/\/pubs.acs.org\/doi\/abs\/10.1021\/jp5127738\" target=\"_blank\" rel=\"noopener noreferrer\"><span style=\"text-decoration: underline\">Visible Light Sensitized CO<sub>2<\/sub> Activation by the Tetraaza [Co<sup>II<\/sup>N<sub>4<\/sub>H(MeCN)]<sup>2+<\/sup> Complex Investigated by FT-IR Spectroscopy and DFT Calculations<\/span><\/a>. <em>J.<\/em>\u00a0<em> Phys. Chem. C. <\/em>(2015), <em>119<\/em>, 4645-4654.<\/p>\n<p><strong>9.<\/strong> Soriaga, M. P; Baricuatro, J. H.; Cummins, K. D.; Kim, Y. G.; Saadi, F. H.; Sun, G.; McCrory, C. C. L.; McKone, J. R.; Velazquez, J. M.; Ferrer, I. M.; Carim, A. I.; Javier, A.; Chmielowiec, B.; Lacy, D. C.; Gregoire, J. M.; Sanabria-Chinchilla, J.; Amashukeli, X. Royea, W. J.; Brunschwig, B. S.; Hemminger, J. C.; Lewis, N. S.; Stickney, J. L.; <a href=\"https:\/\/www.sciencedirect.com\/science\/article\/pii\/S0039602814002088\" target=\"_blank\" rel=\"noopener noreferrer\"><span style=\"text-decoration: underline\">Electrochemical surface science twenty years later: Expeditions into the electrocatalysis of reactions at the core of artificial photosynthesis<\/span><\/a>. <em>Surface Science<\/em> (2015) <em>631<\/em>, 285-294.<\/p>\n<p><strong>8.<\/strong> Lacy, David C.; McCrory, C. C. L; Peters,* J. C.; <a href=\"https:\/\/pubs.acs.org\/doi\/abs\/10.1021\/ic403122j\" target=\"_blank\" rel=\"noopener noreferrer\"><span style=\"text-decoration: underline\">Studies of Cobalt-Mediated Electrocatalytic CO<sub>2<\/sub> Reduction Using a Redox-Active Ligand<\/span><\/a>. <em>Inorg.<\/em>\u00a0<em>Chem. <\/em>(2014) <em>53<\/em>, 4980-4988.<\/p>\n<p><strong>7.<\/strong> Usharani, D.; Lacy, D. C.; Borovik,* A. S.; Shaik,* S.; <span style=\"text-decoration: underline\"><a href=\"https:\/\/pubs.acs.org\/doi\/abs\/10.1021\/ja408073m\" target=\"_blank\" rel=\"noopener noreferrer\">Dichotomous Hydrogen Atom Transfer vs Proton-Coupled Electron Transfer During Activation of X\u2013H Bonds (X = C, N, O) by Nonheme Iron\u2013Oxo Complexes of Variable Basicity<\/a><\/span>. <em>J.<\/em><em>\u00a0Am. Chem. Soc. <\/em>(2013) <em>135<\/em>, 17090-17104.<\/p>\n<p><strong>6.<\/strong> Lacy, David C.; Mukherjee, J.; Lucas, R. L.; Day, V. W.; Borovik,* A. S.; <span style=\"text-decoration: underline\"><a href=\"https:\/\/www.sciencedirect.com\/science\/article\/pii\/S0277538712007255\" target=\"_blank\" rel=\"noopener noreferrer\">Metal Complexes with Varying Intramolecular Hydrogen Bonding Networks<\/a><\/span>. <em>Polyhedron <\/em>(2013) <em>52<\/em>, 261-267.<\/p>\n<p><strong>5.<\/strong> Lacy, David C., Park, Y. J.; Ziller, J. W.; Yano, J.; Borovik,* A. S.; <a href=\"https:\/\/pubs.acs.org\/doi\/abs\/10.1021\/ja304525n\" target=\"_blank\" rel=\"noopener noreferrer\"><span style=\"text-decoration: underline\">Assembly and Properties of Heterobimetallic Co<sup>II\/III<\/sup>\/Ca<sup>II<\/sup> Complexes with Aquo and Hyrdroxo Ligands<\/span><\/a>. <em>J.<\/em>\u00a0<em>Am. Chem. Soc<\/em>. (2012) <em>134<\/em>, 17526-17535.<\/p>\n<p><strong>4.<\/strong> Gupta, R.; Lacy, D. C.; Borovik, A. S.;* Hendrich P.;* <a href=\"https:\/\/pubs.acs.org\/doi\/abs\/10.1021\/ja303224p\" target=\"_blank\" rel=\"noopener noreferrer\"><span style=\"text-decoration: underline\">Electron Paramagnetic Resonance and M\u00f6ssbauer Spectroscopy and Density Functional Theory Analysis of a High-Spin Fe<sup>IV<\/sup>\u2013Oxo Complex<\/span><\/a>. <em>J.<\/em><em>\u00a0Am. Chem. Soc<\/em>. (2012) <em>134<\/em>, 9775-9784.<\/p>\n<p><strong>3.<\/strong> Nguyen, A. I.; Zarkesh, R. A.; Lacy, D. C.; Thorson, M. K.; Heyduk,* A. F.; <span style=\"text-decoration: underline\"><a href=\"http:\/\/pubs.rsc.org\/en\/content\/articlelanding\/2011\/sc\/c0sc00414f#!divAbstract\" target=\"_blank\" rel=\"noopener noreferrer\">Catalytic nitrene transfer by a zirconium(IV) redox-active\u00a0ligand\u00a0complex<\/a><\/span>.\u00a0<em>Chem.\u00a0<\/em><em>Sci.<\/em> (2011) <em>2<\/em>, 166-169.<\/p>\n<p><strong>2.<\/strong> Lacy, David C.; Gupta, R.; Stone, K. L.; Greaves, J.; Ziller, J. W.; Hendrich,* M. P.; Borovik,* A. S.; <span style=\"text-decoration: underline\"><a href=\"https:\/\/pubs.acs.org\/doi\/abs\/10.1021\/ja1047818\" target=\"_blank\" rel=\"noopener noreferrer\">Formation, Structure, and EPR Detection of a High Spin Fe(IV)-Oxo Species Derived from Either an Fe(III)-Oxo or Fe(III)-OH Complex<\/a><\/span>. <em>J.\u00a0<\/em><em>Am. Chem. Soc.<\/em> (2010) <em>132<\/em>, 12188-12190.<\/p>\n<p><strong>1.<\/strong> Margulieux, G. W.; Weidemann, N.; Lacy, D. C.; Moore, C. E.; Rheingold, A. L; Figueroa, J. S.; <a href=\"https:\/\/pubs.acs.org\/doi\/abs\/10.1021\/ja1012382\" target=\"_blank\" rel=\"noopener noreferrer\"><span style=\"text-decoration: underline\">Isocyano Analogues of [Co(CO)<sub>4<\/sub>]<em><sup>n<\/sup><\/em>: A Tetraisocyanide of Cobalt Isolated in Three States of Charge<\/span><\/a>. <em>J.\u00a0<\/em><em>Am. Chem. Soc.<\/em> (2010) <em>132<\/em>, 5033-5035.<\/p>\n","protected":false},"excerpt":{"rendered":"<p>Selected Publications Bench-stable Mn(III)Cl3JACS 2022The Cl-atom in a bottleJACS 2023Bench-stable powerful oxidantsJACS 2024MnX3 with phosphine ligandsInorg. Chem. 2024 Link to Google Scholar (* = corresponding author;\u00a0\u2021 = undergraduate authors;\u00a0\u00a7 = &hellip; <a href=\"https:\/\/ubwp.buffalo.edu\/lacylab\/publications\/\" class=\"more-link\">Continue reading <span class=\"screen-reader-text\">Publications<\/span> <span class=\"meta-nav\">&rarr;<\/span><\/a><\/p>\n","protected":false},"author":277,"featured_media":0,"parent":0,"menu_order":0,"comment_status":"closed","ping_status":"closed","template":"","meta":{"footnotes":""},"class_list":["post-33","page","type-page","status-publish","hentry"],"_links":{"self":[{"href":"https:\/\/ubwp.buffalo.edu\/lacylab\/wp-json\/wp\/v2\/pages\/33","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/ubwp.buffalo.edu\/lacylab\/wp-json\/wp\/v2\/pages"}],"about":[{"href":"https:\/\/ubwp.buffalo.edu\/lacylab\/wp-json\/wp\/v2\/types\/page"}],"author":[{"embeddable":true,"href":"https:\/\/ubwp.buffalo.edu\/lacylab\/wp-json\/wp\/v2\/users\/277"}],"replies":[{"embeddable":true,"href":"https:\/\/ubwp.buffalo.edu\/lacylab\/wp-json\/wp\/v2\/comments?post=33"}],"version-history":[{"count":126,"href":"https:\/\/ubwp.buffalo.edu\/lacylab\/wp-json\/wp\/v2\/pages\/33\/revisions"}],"predecessor-version":[{"id":939,"href":"https:\/\/ubwp.buffalo.edu\/lacylab\/wp-json\/wp\/v2\/pages\/33\/revisions\/939"}],"wp:attachment":[{"href":"https:\/\/ubwp.buffalo.edu\/lacylab\/wp-json\/wp\/v2\/media?parent=33"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}