{"id":33,"date":"2018-05-23T19:26:54","date_gmt":"2018-05-23T19:26:54","guid":{"rendered":"http:\/\/wpdev.acsu.buffalo.edu\/dclubchem\/?page_id=33"},"modified":"2025-02-19T14:41:23","modified_gmt":"2025-02-19T14:41:23","slug":"publications","status":"publish","type":"page","link":"https:\/\/ubwp.buffalo.edu\/lacylab\/publications\/","title":{"rendered":"Publications"},"content":{"rendered":"

University at Buffalo Publications<\/h1>\n

(* = corresponding author;\u00a0\u2021<\/sup> = undergraduate authors;\u00a0\u00a7<\/sup><\/em> = equally contributing)<\/p>\n

Published manuscripts<\/em><\/strong><\/p>\n

33<\/strong>. Roche-Rivera, Z.; Abhyankar, P. C.; Crawley, M. R.; Lacy,* D. C. Synthesis of Ph3<\/sub>PO-stabilized Mo(V) and (VI) imido complexes. J. Coord. Chem. <\/em>2025<\/strong>, in press. https:\/\/doi.org\/10.1080\/00958972.2025.2453066<\/a><\/p>\n

\n
\"\"<\/a><\/div>\n<\/div>\n

32<\/strong>. Saju, A.; Crawley, M. R.; MacMillan, S. N.; Le Magueres, P.; Del Campo, M.; Lacy.* D. C. N<\/em>-oxide coordination to Mn(III) chloride<\/span>. Molecules<\/em> 2024<\/strong>,\u00a0 29<\/em>(19), 4670. DOI: https:\/\/doi.org\/10.3390\/molecules29194670<\/a><\/p>\n

\"\"<\/a><\/div>\n

31<\/strong>. Paul, S.; Saju, A.; Cohen, C.; Crawley, M. R.; MacMillan, S. N.; Lacy.* D. C. Synthesis of MnX3<\/sub> (X = Cl, Br, I) compounds with phosphine (R3<\/sub>P) ligands<\/span>. Inorg. Chem. <\/em>2024<\/strong>, 63<\/em>, 15791-15803. DOI: https:\/\/doi.org\/10.1021\/acs.inorgchem.4c01820<\/a><\/span><\/p>\n

\"\"<\/a><\/div>\n

30<\/strong>. Saju, A.; Crawley, M. R.; MacMillan, S. N.; Lacy.* D. C. Manganese(III) nitrate complexes as bench-stable powerful oxidants<\/span>. J. Am. Chem. Soc.<\/em> 2024<\/strong>,\u00a0146<\/em>, 11616\u201311621<\/span>. DOI: https:\/\/doi.org\/10.1021\/jacs.4c03411<\/a><\/p>\n

\"\"<\/a><\/div>\n

29<\/strong>. Lacy,* D. C.; Heppner,* D. E.; Buckley,\u00a7 <\/sup>B.; Griffiths,\u00a7<\/sup> J.; Gunasekera,\u00a7<\/sup> P. S.; Patel,\u00a7<\/sup> P.; Roche-Rivera,\u00a7\u2021<\/sup> Z.; Coppola,\u2021 <\/sup>K.; Dempsey,\u2021<\/sup> K.; Pillai,\u2021<\/sup> S.; Renzoni\u2021<\/sup> B.; Twelve CO molecules for the price of one. A simple water-soluble CORM, [Mn(CO)3<\/sub>(\u00b5-OH)]4<\/sub><\/span>. Polyhedron<\/em> 2024<\/strong>,\u00a0251<\/em>, 116859. DOI: https:\/\/doi.org\/10.1016\/j.poly.2024.116859<\/a>
\n<\/em><\/p>\n

\"\"<\/a><\/div>\n

28<\/strong>. Gunasekera, P. S.; Paul, S.; MacMillan, S. N.; Lacy,* D. C. Synthesis and characterization of dearomatized pyridine-derived alkyl-amido-tert<\/em>-butylphosphine iron(II) complexes<\/u>. Eur. J. Inorg. Chem. <\/em>2024<\/strong>,\u00a027<\/em>, e202300757. DOI: https:\/\/doi.org\/10.1002\/ejic.202300757<\/a><\/p>\n

\"\"<\/a><\/div>\n

27<\/strong>. Saju,\u00a7<\/sup><\/em> A.; Gunasekera,\u00a7<\/sup><\/em> P. S.; Morgante, P.; MacMillan, S. N.; Autschbach,* J.; Lacy,* D. C. Experimental and Computational Determination of a M\u2013Cl Homolytic Bond Dissociation Free Energy: Mn(III)Cl Mediated C\u2013H Cleavage and Chlorination<\/a>. J. Am. Chem. Soc.<\/em> 2023<\/strong>,\u00a0145<\/em>, 13384\u201313391<\/span>. DOI: 10.1021\/jacs.3c03651.<\/p>\n

\"\"<\/a><\/div>\n
<\/div>\n

26<\/strong>. Lacy,* D. C.; Abhyankar, P. C. Dinuclear Mn(I) complexes with phosphido and hydrido bridges: synthesis, reactivity, and hydrogenative catalysis<\/a> Chem. Eur. J. <\/em>2023<\/strong>, e202300518.<\/p>\n

\"\"<\/a><\/div>\n
<\/div>\n

25<\/strong>. Saju, A.; Griffiths, J. R.; MacMillan, S. N.; Lacy,* D. C. Synthesis of a bench-stable manganese(III) chloride compound: coordination chemistry and alkene dichlorination<\/a>\u00a0J. Am. Chem. Soc.<\/em> 2022<\/strong>, 144<\/em>, 16761.<\/p>\n

\"\"<\/a><\/p>\n

24<\/strong>. Abhyankar, P. C.; MacMillan, S. N.; Lacy,* D. C. Bench-stable dinuclear Mn(I) catalysts in E-selective alkyne semihydrogenation: a mechanistic investigation<\/a> Chem., Eur. J. <\/em>2022<\/strong>, 28, <\/em>e202201766.<\/p>\n

\"\"<\/a><\/p>\n

23<\/strong>. Paul, S.; Morgante, P.; MacMillan, S. N.; Autschbach,* J.; Lacy,* D. C. Hydrogenative catalysis with three-coordinate zinc complexes supported with PN ligands is enhanced compared to PNP analogs<\/span><\/a> Chem., Eur. J. <\/i>2022<\/strong>, 28<\/em>, e202201042.<\/p>\n

\"\"<\/p>\n

22<\/strong>. Abhyankar, P. C.; MacMillan, S. N.; Lacy,* D. C. Activation of H2<\/sub> with dinuclear manganese(I)-phosphido complexes<\/span><\/a> Organometallics <\/i>2022<\/strong>,\u00a041<\/em>, 60-66.<\/p>\n

\"\"<\/strong><\/p>\n

21<\/strong>. Vigneswaran, V.; Abhyankar, P. C.; MacMillan, S. N.; Lacy,* D. C. H2<\/sub> activation across manganese(I)-C bonds: atypical metal-ligand cooperativity in the aromatization\/dearomatization paradigm<\/span><\/a> Organometallics <\/i>2022<\/strong>, 41<\/i>, 67-75.<\/p>\n

\"\"<\/p>\n

20<\/strong>. Fanara,\u00a7<\/sup><\/em> P. M.; Vigneswaran,\u00a7<\/sup><\/em> V.; Gunasekera, P. S.; MacMillan, S. N.; Lacy,* D. C. Reversible photoisomerization in a Ru cis-dihydride catalyst accessed through atypical metal\u2013ligand cooperative H2<\/sub> activation: photoenhanced acceptorless alcohol dehydrogenation<\/span><\/a> \u00a0Organometallics <\/i>2022<\/strong>,\u00a0<\/i>41<\/em>, 93-98.<\/p>\n

\"\"<\/p>\n

19<\/strong>. Lacy,* D. C.; Paul, S.; Vigneswaran, V.; Abhyankar, P. C. Carbonyl and Isocyanide Complexes of Manganese<\/u><\/a>, Chapter 6.06 Comprehensive Organometallic Chemistry IV;<\/em> Elsevier 2021<\/strong>, 6<\/em>, 449-552.<\/p>\n

\"\"<\/a><\/p>\n

18<\/strong>. Gunasekera, P. S.; MacMillan, S. N.; Lacy,* D. C. Synthesis and coordination of a tert<\/em>-butyl functionalized facially coordinating 2-histidine 1-carboxylate model ligand<\/span><\/a>.\u00a0J. Coord. Chem<\/em>.\u00a02021<\/strong>,\u00a074<\/em>, 315-320.<\/p>\n

\"\"<\/p>\n

17<\/strong>. Gunasekera, P. S.; Abhyankar, P. C.; MacMillan, S. N.; Lacy,* D. C. A facially coordinating tris-benzimidazole ligand for nonheme iron enzyme models<\/span><\/a>. Eur. J. Inorg. Chem. <\/em>2021<\/strong>, 2021<\/em>, 654-657.<\/p>\n

\"\"<\/p>\n

16<\/strong>. Fanara, P. M.; MacMillan, S. N.;\u00a0 Lacy,* D. C. Planar-locked Ru-PNN catalysts in 1-phenylethanol dehydrogenation<\/u><\/a>. \u00a0Organometallics<\/em>, 2020<\/strong>, 39<\/em>, 3628-3644.<\/p>\n

\"\"<\/p>\n

15<\/strong>. Kadassery, K. J.; Crawley, M. R.; MacMillan, S. N.; Lacy,* D. C. A Hemilabile Manganese(I)-Phenol Complex and its Coordination Induced O\u2013H Bond Weakening<\/a>. Dalton Trans.<\/em>\u00a02020<\/b>, <\/i>49<\/em>, 16217-16255.<\/span><\/p>\n

\"\"<\/p>\n

14<\/strong>. Vigneswaran, V.; MacMillan, S. N.; Lacy,* D. C. Beta-Amino Phosphine Mn Catalysts for 1,4-Transfer Hydrogenation of Chalcones and Allylic Alcohol Isomerization<\/a>.\u00a0Organometallics<\/em>\u00a02019<\/b>, 38<\/span>, <\/span><\/i>4387-4391.<\/span><\/p>\n

\"\"<\/p>\n

13<\/strong>. Lacy,* D. C. Applications of the Marcus Cross Relation to Inner Sphere O2<\/sub> Reduction: Implications in Small Molecule Activation<\/a>. Inorg. Chem. Front.\u00a0 <\/em>2019<\/strong>, 6<\/em>, 2396-2403.<\/p>\n

\"\"<\/p>\n

12<\/strong>. Kadassery, K. J.;\u00a0MacMillan, S. N.; Lacy,* D. C. Resurgence of Organomanganese(I) Chemistry. Bidentate Phosphine-Phenol(ate) Mn(I) Complexes<\/span><\/a>. Inorg. Chem.\u00a0<\/em>2019<\/strong>, 58<\/em>, 10527-10535<\/span>.<\/p>\n

\"\"<\/p>\n

11<\/strong>. Crawley, M. R.; Kadassery, K. J.; Oldacre, A. N.; Freidman, A. E.; Lacy,* D. C.; Cook,* T. R. Rhenium(I) phosphazane complexes for electrocatalytic CO2<\/sub> reduction<\/u><\/a>. Organometallics.<\/em>\u00a0\u00a02019<\/strong>,\u00a038<\/span>, 1664\u20131676.<\/p>\n

\"\"<\/p>\n

10<\/strong>. Kadassery,\u00a7<\/sup><\/em> K. J.; Sethi,\u00a7\u00a0<\/sup><\/em>K.; Fanara, P. M.; Lacy,* D. C. CO-photolysis-induced H-atom transfer from Mn(I)O\u2013H bonds<\/a>.\u00a0<\/em>\u00a0Inorg. Chem<\/em>.\u00a02019,\u00a0<\/strong>58<\/span><\/em>, 4679\u20134685.<\/p>\n

\"\"<\/p>\n

9<\/strong>. Kadassery, K. J.; Lacy,* D. C. Pentacarbonylmethylmanganese(I) as a synthon for Mn(I) pincer catalysts<\/a>.<\/em>\u00a0\u00a0Dalton Trans<\/em>.\u00a02019<\/strong>,\u00a048<\/em>, 4467 – 4470.<\/p>\n

<\/div>\n

\"\"<\/p>\n

8<\/strong>. Cannella, A. F.; Surendhran,\u2021<\/sup> R.; MacMillan, S. N.; Gupta, R.; Lacy,* D. C. Electronically varied manganese tris-arylacetamide tripodal complexes<\/span><\/a>. J. Coord. Chem<\/em>.\u00a02019<\/strong>, 72<\/em>,\u00a01287-1297. Article in “Emerging Leader Issue”<\/p>\n

\"\"<\/p>\n

7<\/strong>. Guan, Y.-S.; Zhong, G.; Hu, Y.; Cannella, A. F.; Li, C.; Lee, N.; Jia,* Q.; Lacy,* D. C.; Ren,* S. Magnetoelectric radical hydrocarbons<\/u><\/a>. Adv. Mater.<\/em>\u00a02018<\/strong>,\u00a031<\/em>, 1806263.<\/span><\/p>\n

<\/p>\n

6<\/strong>. Andrews, J. L.; Cho, J.; Wangoh, L.; Suwandaratne, N.; Sheng, A.; Chauhan S.; Nieto, K.; Mohr, A.; Kadassery, K. J.; Popeil, M. R.; Thakur, P. K.; Sfeir, M.; Lacy, D. C.; Lee, T.-L.; Zhang, P.; Watson,* D. F.; Piper,* L. F. J.; Banerjee,* S.; Hole extraction by design in photocatalytic architectures interfacing CdSe quantum dots with topochemically-stabilized tin vanadium oxide<\/u><\/a>. J. Am. Chem. Soc. <\/em>2018<\/strong>,\u00a0140<\/em>, 17163-17174.<\/p>\n

\"\"<\/p>\n

5<\/strong>. Kadassery, K. J.; MacMillan, S. N.; Lacy,* D. C. Bisphosphine phenol and phenolate complexes of Mn(I): Manganese(I) catalyzed Tishchenko reaction<\/a>\u00a0Dalton. Trans.\u00a0<\/em>2018<\/strong>, 47<\/em>,\u00a012652-12655.<\/p>\n

\"\"<\/p>\n

4<\/strong>. Surendhran,\u2021<\/sup> R.;\u00a0D\u2019Arpino,\u2021<\/sup> A. A.; Sciscent,\u2021<\/sup>\u00a0B. Y.;\u00a0Cannella, A. F.; Friedman, A. E.; MacMillan, S. N.; Rupal, G.; Lacy,* D. C.\u00a0Deciphering the Mechanism of O2<\/sub> Reduction with Electronically Tunable Non-Heme Iron Enzyme Model Complexes<\/u><\/a> Chem. Sci.<\/em> 2018<\/strong>, <\/i><\/b>9<\/em>, 5773-5780.<\/p>\n

\"\"<\/p>\n

3<\/strong>. Cannella, A. F.;\u00a0Dey, S. K. MacMillan, S. N.; Lacy,* D. C.\u00a0Structural Diversity in Pyridine and Polypyridine Adducts of Ring Slipped Manganocene: Correlating Ligand Steric Bulk with Quantified Deviation from Ideal Hapticity<\/a>.\u00a0Dalton Trans.<\/em>\u00a02018<\/strong>,\u00a0<\/strong>47<\/em>, 5171-5180. Cover article for 2018 issue 15.<\/p>\n

\"\"<\/p>\n

2<\/strong>. Kadassery, K. J.; Dey, S. K.; Cannella, A. F.; Surendhran,\u2021<\/sup> R. Lacy,* D. C. Photochemical Water Splitting with Organomanganese Complexes<\/a>.<\/em>\u00a0Inorg. Chem.<\/em>2017<\/span><\/strong>,\u00a056<\/span><\/em>\u00a0(16), 9954\u20139965.<\/p>\n

\"\"<\/p>\n

1<\/strong>. Kadassery, K. J.; Dey, S. K.; Friedman, A. E.; Lacy,* D. C. Exploring the Role of Carbonate in the Formation of an Organomanganese Tetramer<\/a>. Inorg. Chem. <\/em>2017<\/strong>,\u00a056<\/span><\/em>\u00a0(15), 8748\u20138751.<\/p>\n

\"\"<\/p>\n

University of California-Irvine and California Institute of Technology affiliated publications<\/h1>\n
    \n
  1. Hill, E. A.; Weitz, A. C.; Onderko, E.; Romero-Rivera, A.; Guo,* Y.; Swart,* M.; Bominaar,* E. L.; Green,* M. T.; Hendrich,* M. P.; Lacy,* D. C.; Borovik,* A. S.; Reactivity of an Fe(IV)-Oxo Complex with Protons and Oxidants<\/a><\/span>.\u00a0J. Am. Chem. Soc. <\/em>(2016),\u00a0138<\/em>, 13143-13146.<\/li>\n
  2. Lacy, David C.; Roberts,\u2021<\/sup> G. M.;\u00a0Peters,* J. C.; The Cobalt Hydride that Never Was: Revisiting Schrauzer\u2019s \u201cHydridocobaloxime.\u201d<\/span><\/a> J.<\/em>\u00a0Am. Chem. Soc. <\/em>(2015) 137<\/em>, 4860-4684.<\/li>\n
  3. Sieh,\u00a7<\/sup><\/em> D.; Lacy,\u00a7<\/sup><\/em> D. C. ; Peters,* J. C.; Kubiak,* C. P.; Reduction of CO2<\/sub> by pyridine monoamine molybdenum carbonyl complexes: Cooperative Metal-Ligand Binding of CO2<\/sub><\/span><\/a>. Chem., Eur. J<\/em>. (2015) 21<\/em>, 8497-8503. \u00a7 = Equally contributing<\/li>\n
  4. Zhang, M.; El-Roz, M.; Mendoza-Cortez, J. L.; Lacy, D. C.; Peters,* J. C.; Head-Gordon,* M.; Frei,* H.; Visible Light Sensitized CO2<\/sub> Activation by the Tetraaza [CoII<\/sup>N4<\/sub>H(MeCN)]2+<\/sup> Complex Investigated by FT-IR Spectroscopy and DFT Calculations<\/span><\/a>. J.<\/em>\u00a0 Phys. Chem. C. <\/em>(2015), 119<\/em>, 4645-4654.<\/li>\n
  5. Soriaga, M. P; Baricuatro, J. H.; Cummins, K. D.; Kim, Y. G.; Saadi, F. H.; Sun, G.; McCrory, C. C. L.; McKone, J. R.; Velazquez, J. M.; Ferrer, I. M.; Carim, A. I.; Javier, A.; Chmielowiec, B.; Lacy, D. C.; Gregoire, J. M.; Sanabria-Chinchilla, J.; Amashukeli, X. Royea, W. J.; Brunschwig, B. S.; Hemminger, J. C.; Lewis, N. S.; Stickney, J. L.; Electrochemical surface science twenty years later: Expeditions into the electrocatalysis of reactions at the core of artificial photosynthesis<\/span><\/a>. Surface Science<\/em> (2015) 631<\/em>, 285-294.<\/li>\n
  6. Lacy, David C.; McCrory, C. C. L; Peters,* J. C.; Studies of Cobalt-Mediated Electrocatalytic CO2<\/sub> Reduction Using a Redox-Active Ligand<\/span><\/a>. Inorg.<\/em>\u00a0Chem. <\/em>(2014) 53<\/em>, 4980-4988.<\/li>\n
  7. Usharani, D.; Lacy, D. C.; Borovik,* A. S.; Shaik,* S.; Dichotomous Hydrogen Atom Transfer vs Proton-Coupled Electron Transfer During Activation of X\u2013H Bonds (X = C, N, O) by Nonheme Iron\u2013Oxo Complexes of Variable Basicity<\/a><\/span>. J.<\/em>\u00a0Am. Chem. Soc. <\/em>(2013) 135<\/em>, 17090-17104.<\/li>\n
  8. Lacy, David C.; Mukherjee, J.; Lucas, R. L.; Day, V. W.; Borovik,* A. S.; Metal Complexes with Varying Intramolecular Hydrogen Bonding Networks<\/a><\/span>. Polyhedron <\/em>(2013) 52<\/em>, 261-267.<\/li>\n
  9. Lacy, David C., Park, Y. J.; Ziller, J. W.; Yano, J.; Borovik,* A. S.; Assembly and Properties of Heterobimetallic CoII\/III<\/sup>\/CaII<\/sup> Complexes with Aquo and Hyrdroxo Ligands<\/span><\/a>. J.<\/em>\u00a0Am. Chem. Soc<\/em>. (2012) 134<\/em>, 17526-17535.<\/li>\n
  10. Gupta, R.; Lacy, D. C.; Borovik, A. S.;* Hendrich P.;* Electron Paramagnetic Resonance and M\u00f6ssbauer Spectroscopy and Density Functional Theory Analysis of a High-Spin FeIV<\/sup>\u2013Oxo Complex<\/span><\/a>. J.<\/em>\u00a0Am. Chem. Soc<\/em>. (2012) 134<\/em>, 9775-9784.<\/li>\n
  11. Nguyen, A. I.; Zarkesh, R. A.; Lacy, D. C.; Thorson, M. K.; Heyduk,* A. F.; Catalytic nitrene transfer by a zirconium(IV) redox-active\u00a0ligand\u00a0complex<\/a><\/span>.\u00a0Chem.\u00a0<\/em>Sci.<\/em> (2011) 2<\/em>, 166-169.<\/li>\n
  12. Lacy, David C.; Gupta, R.; Stone, K. L.; Greaves, J.; Ziller, J. W.; Hendrich,* M. P.; Borovik,* A. S.; Formation, Structure, and EPR Detection of a High Spin Fe(IV)-Oxo Species Derived from Either an Fe(III)-Oxo or Fe(III)-OH Complex<\/a><\/span>. J.\u00a0<\/em>Am. Chem. Soc.<\/em> (2010) 132<\/em>, 12188-12190.<\/li>\n
  13. Margulieux, G. W.; Weidemann, N.; Lacy, D. C.; Moore, C. E.; Rheingold, A. L; Figueroa, J. S.; Isocyano Analogues of [Co(CO)4<\/sub>]n<\/sup><\/em>: A Tetraisocyanide of Cobalt Isolated in Three States of Charge<\/span><\/a>. J.\u00a0<\/em>Am. Chem. Soc.<\/em> (2010) 132<\/em>, 5033-5035.<\/li>\n
  14. Book Chapter <\/em>Cook, S. A.; Lacy, D. C.; Borovik, A. S.; Terminal Metal-Oxo Species with Unusual Spin States<\/a><\/span>. Book Chapter in Spin States in Biochemistry and Inorganic Chemistry: Influence on Structure and Reactivity<\/em> Swart, M. and Costas M.; John Wiley & Sons, Ltd., 2016<\/li>\n<\/ol>\n","protected":false},"excerpt":{"rendered":"

    University at Buffalo Publications (* = corresponding author;\u00a0\u2021 = undergraduate authors;\u00a0\u00a7 = equally contributing) Published manuscripts 33. Roche-Rivera, Z.; Abhyankar, P. C.; Crawley, M. R.; Lacy,* D. C. Synthesis of … <\/p>\n

    Continue reading “Publications”<\/span><\/a><\/p>\n","protected":false},"author":277,"featured_media":0,"parent":0,"menu_order":0,"comment_status":"closed","ping_status":"closed","template":"","meta":{"footnotes":""},"class_list":["post-33","page","type-page","status-publish","hentry"],"_links":{"self":[{"href":"https:\/\/ubwp.buffalo.edu\/lacylab\/wp-json\/wp\/v2\/pages\/33","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/ubwp.buffalo.edu\/lacylab\/wp-json\/wp\/v2\/pages"}],"about":[{"href":"https:\/\/ubwp.buffalo.edu\/lacylab\/wp-json\/wp\/v2\/types\/page"}],"author":[{"embeddable":true,"href":"https:\/\/ubwp.buffalo.edu\/lacylab\/wp-json\/wp\/v2\/users\/277"}],"replies":[{"embeddable":true,"href":"https:\/\/ubwp.buffalo.edu\/lacylab\/wp-json\/wp\/v2\/comments?post=33"}],"version-history":[{"count":102,"href":"https:\/\/ubwp.buffalo.edu\/lacylab\/wp-json\/wp\/v2\/pages\/33\/revisions"}],"predecessor-version":[{"id":774,"href":"https:\/\/ubwp.buffalo.edu\/lacylab\/wp-json\/wp\/v2\/pages\/33\/revisions\/774"}],"wp:attachment":[{"href":"https:\/\/ubwp.buffalo.edu\/lacylab\/wp-json\/wp\/v2\/media?parent=33"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}