{"id":26,"date":"2022-07-26T22:48:54","date_gmt":"2022-07-26T22:48:54","guid":{"rendered":"https:\/\/wpdev.acsu.buffalo.edu\/chemlerlab\/?page_id=26"},"modified":"2023-12-20T20:03:43","modified_gmt":"2023-12-20T20:03:43","slug":"publications","status":"publish","type":"page","link":"https:\/\/ubwp.buffalo.edu\/chemlerlab\/publications\/","title":{"rendered":"Publications"},"content":{"rendered":"\n

84. J. J. Kennedy-Ellis, A. D. Kelleher, J. A. Sayeed, A. S. Burde and S. R. Chemler,* (2024<\/strong>) \u201cEnantioenriched allylesters via a copper-catalyzed diene carboesterification with alkyltrifluoroborates and carboxylic acids,\u201d accepted<\/em> in J. Org. Chem<\/em>.<\/p>\n\n\n\n

83. S. R. Chemler (2024), “Copper-catalyzed Generation of Nitrogen-centered Radicals and Reactions Thereof,” submitted to Arkivoc as an invited contribution for Prof. Samir Zard’s honorary issue.<\/p>\n\n\n\n

82. R. L. L. Carmo, S. L. Galster, T. Wdowik, C. Song, S. R. Chemler* (2023<\/strong>), “Copper-Catalyzed Enantioselective Aerobic Alkene Aminooxygenation and Dioxygenation: Access to 2-Formyl Saturated Heterocycles and Unnatural Proline Derivatives,” J. Am. Chem. Soc.<\/em> 2023, 145, 13715-13729. https:\/\/pubs-acs-org.gate.lib.buffalo.edu\/doi\/10.1021\/jacs.3c01985<\/p>\n\n\n\n

81.  S. R. Chemler* and J. J. Kennedy-Ellis (2022<\/strong>), \u201cCopper-Catalyzed Alkene Difunctionalizations,\u201d in press<\/em>, Base-Metal Catalysis, Science of Synthesis, N. Yoshikal, Ed.<\/p>\n\n\n\n

80. A. S. Burde, S. R. Chemler* (2022)<\/strong>, \u201cCopper-Catalyzed Enantioselective Oxysulfenylation of Alkenols: Synthesis of Arylthiomethyl-Substituted Cyclic Ethers,\u201d ACS Catalysis<\/em>, 12, 7559-7564.  https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/acscatal.2c02214<\/a><\/p>\n\n\n\n

79. J. Li, R. Lama, S. L. Galster, J. R. Inigo, J. Wu, D. Chandra, S. R. Chemler, X. Wang* (2022<\/strong>), \u201cSmall Molecule MMRi62 Induces Ferroptosis and Inhibits Metastasis in Pancreatic  Cancer via Degradation of Ferritin Heavy Chain and Mutant p53, Molecular Cancer Therapeutics, 21, 535-545. https:\/\/aacrjournals.org\/mct\/article-abstract\/21\/4\/535\/689573\/Small-Molecule-MMRi62-Induces-Ferroptosis-and?redirectedFrom=fulltext<\/a><\/p>\n\n\n\n

78. I. A. Berhane, A. S. Burde, J. J. Kennedy-Ellis, E. Zurek and S. R. Chemler* (2021<\/strong>), \u201cCopper-Catalyzed Enantioselective Alkene Carboetherification for the Synthesis of Saturated Six-Membered Cyclic Ethers,\u201d Chem. Commun<\/em>., 57, 10099-10102. https:\/\/pubs.rsc.org\/en\/content\/articlelanding\/2021\/cc\/d1cc03515k<\/a><\/p>\n\n\n\n

77. S. R. Chemler,* D. Chen, S. D. Karyakarte, J. M. Shikora, T. Wdowik (2021<\/strong>), \u201cTransition Metal Catalyzed Aminooxygenation of Alkenes,\u201d Organic Reactions, 108<\/em>, 421-962.  https:\/\/www.wiley.com\/en-us\/Organic+Reactions,+Volume+108-p-9781119832072<\/a><\/p>\n\n\n\n

76. A. J. Pradhan, D. Lu, L. R. Parisi, S. Shen, I. A. Berhane, S. L. Galster, K. Bynum, V. Monje-Galvan, O. Gokcumen, S. R. Chemler, J. Qu, J. G. Kay, G. E. Atilla-Gokcumen* (2021<\/strong>), \u201cProtein Acylation by Saturated Very Long Chain Fatty Acids and Endocytosis are Involved in Necroptosis,\u201d Cell Chem. Biol<\/em>., 28, 1298. https:\/\/pubmed.ncbi.nlm.nih.gov\/33848465\/<\/a><\/p>\n\n\n\n

75. A. S. Burde, S. D. Karyakarte,E. D. Sylvester, S. R. Chemler* (2021<\/strong>), \u201cCopper-Catalyzed Enantioselective Synthesis of Bridged Bicyclic Ketals from 1,1-Disubstituted-4-methylene-1,6-hexanediols and Related Alkenols,\u201d Chem. Commun<\/em>., 57, 105-108. https:\/\/pubs.rsc.org\/en\/content\/articlelanding\/2021\/cc\/d0cc06404a<\/a><\/p>\n\n\n\n

74. J. J. Kennedy-Ellis, E. D. Boldt, S. R. Chemler* (2020<\/strong>), \u201cSynthesis of Benzylureas and Related Amine Derivatives via Copper-catalyzed Three-component Carboamination of Styrenes,\u201d Org. Lett<\/em>., 22, 8365-8369. https:\/\/pubmed.ncbi.nlm.nih.gov\/33074005\/<\/a><\/p>\n\n\n\n

73. T. Wdowik, S. Galster, R. L. de Carmo, S. R. Chemler* (2020<\/strong>), \u201cEnantioselective, Aerobic Copper-Catalyzed Oxidative Cyclization of Alkenols and N-(4-Pentenyl)arylsulfonamides: Synthesis of Fused Ring and Spirocyclic Saturated Heterocycles,\u201d ACS Catalysis<\/em>, 10, 8535. https:\/\/pubs.acs.org\/doi\/abs\/10.1021\/acscatal.0c02607<\/a><\/p>\n\n\n\n

72. D. Chen, I. A. Berhane, S. R. Chemler* (2020<\/strong>), \u201cCopper-Catalyzed Enantioselective Hydroalkoxylation of Alkenols for the Synthesis of Cyclic Ethers,\u201d Org. Lett.<\/em>, 22, 7409-7414. Selected for October 2020 Issue Cover. <\/em>https:\/\/pubs.acs.org\/doi\/abs\/10.1021\/acs.orglett.0c01691<\/a><\/p>\n\n\n\n

71. L. R. Parisi, S. Sowlati-Hashjin, I. A. Berhane, S. L. Galster, K. A. Carter, J. F. Lovell, S. R. Chemler, M. Karttunen, G. E. Atilla-Gokcumen* (2019<\/strong>) \u201cMembrane Disruption by Very Long Chain Fatty Acids During Necroptosis,\u201d ACS Chem. Biol.<\/em>, 14, <\/em>2286-2294.<\/p>\n\n\n\n

70. J. M. Shikora, C. Um, Z. M. Khoder, S. R. Chemler* (2019<\/strong>) \u201cSaturated Oxygen and Nitrogen Heterocycles via Oxidative Coupling of Alkyltrifluoroborates with Alkenols, Alkenoic Acids and Protected Alkenylamines,\u201d Chem. Sci.<\/em>, 10<\/em>, 9265-9269. https:\/\/pubs.rsc.org\/en\/content\/articlelanding\/2019\/sc\/c9sc02835h<\/a><\/p>\n\n\n\n

69. D. Chen, S. R. Chemler* (2018<\/strong>), Synthesis of Phthalans Via Copper-Catalyzed Enantioselective Cyclization\/Carboetherification of 2-Vinylbenzyl Alcohols,\u201d 20<\/em>, 6453-6456.<\/p>\n\n\n\n

68. S. D. Karyakarte, C. Um, I. A. Berhane, S. R. Chemler* (2018<\/strong>), Synthesis of Spirocyclic Ethers by Enantioselective Copper-Catalyzed Carboetherification of Alkenols, Angew. Chem. Int. Ed<\/em>., 57<\/em>, 12921-12924. https:\/\/onlinelibrary.wiley.com\/doi\/abs\/10.1002\/anie.201808554<\/a><\/p>\n\n\n\n

67. J. M. Shikora, S. R. Chemler* (2018<\/strong>), Synthesis of Benzylamines via Copper-Catalyzed Enantioselective Aza-Friedel-Crafts Addition of Phenols to N-Sulfonyl Aldimines, Org. Lett<\/em>. 20, 2133-2137.<\/p>\n\n\n\n

66. T. Wdowik, S. R. Chemler* (2017<\/strong>), Direct Synthesis of 2-Formylpyrrolidines, 2-Pyrrolidinones and 2-Dihydrofuranones Via Aerobic Copper-Catalyzed Aminooxygenation and Dioxygenation of 4-Pentenylsulfonamides and 4-Pentenylalcohols, J. Am. Chem. Soc. <\/em>139, 9515-9518. https:\/\/pubs.acs.org\/doi\/10.1021\/jacs.7b05680<\/a><\/p>\n\n\n\n

65. Z. M. Khoder, C. E. Wong, S. R. Chemler* (2017<\/strong>), Stereoselective Synthesis of Isoxazolidinones Via Copper-Catalyzed Alkene Diamination, ACS Catalysis <\/em>7, 4775-4779.<\/p>\n\n\n\n

64. S. R. Chemler,* S. D. Karyakarte, Z. M. Khoder (2017<\/strong>) \u201cStereoselective and Regioselective Synthesis of Heterocycles Via Copper-Catalyzed Additions of Amine Derivatives and Alcohols to Alkenes,\u201d J. Org. Chem.<\/em>, 82, 11311-11666.  (invited Perspective, Cover of Issue, Nov. 3, dedicated to this review)<\/p>\n\n\n\n

63.       S. R. Chemler* and T. Wdowik (2017<\/strong>), \u201cAminohydroxylation and Aminooxygenation of Alkenes,\u201d Chap. 5.3 in Catalytic Oxidation in Organic Synthesis, Vol. 25, Science of Synthesis, K. Muniz, ed., 1, 343-388.<\/p>\n\n\n\n

62. C. Um, S. R. Chemler* (2016<\/strong>), Synthesis of 2-Aryl and 2-Vinylpyrrolidines Via Copper-Catalyzed Coupling of Styrenes and Dienes with Potassium beta-Aminoethyl Trifluoroborates, Org. Lett<\/em>. 18, 2515-2518.<\/p>\n\n\n\n

61. B. J. Casavant, Z. M. Khoder, I. A. Berhane, S. R. Chemler* (2015<\/strong>), Copper(II) Promoted Cyclization\/Difunctionalization of Allenols and Allenylsulfonamides: Synthesis of Heterocycle Functionalized Vinyl Carboxylates, Org. Lett<\/em>. 17, 5958-5961.<\/p>\n\n\n\n

60. S. Karyakarte, F. C. Sequeira, G. H. Zibreg, G. Huang, J. P. Matthew, M. M. M. Ferreira and S. R. Chemler* (2015<\/strong>), Copper-promoted synthesis of 1,4-benzodiazepinones via alkene diamination, Tetrahedron Lett<\/em>., 56, 3686-3689. (Invited for memorial issue for Harry Wasserman.)<\/p>\n\n\n\n

59. T. W. Liwosz, S. R. Chemler*, (2015<\/strong>) Copper-Catalyzed Synthesis of N<\/em>-Aryl and N<\/em>-Sulfonyl Indoles from 2-Vinylanilines with O2<\/sub> as Terminal Oxidant and TEMPO as Co-Catalyst, Synlett<\/em>, 26, 335-339. (Invited for cluster issue on earth abundant metals in catalysis.)<\/p>\n\n\n\n

58. S. R. Chemler (2015<\/strong>) \u201cCopper Catalysis in Organic Synthesis,\u201d Beilstein J. Org. Chem<\/em>. 11<\/em>, 2252-2253.<\/p>\n\n\n\n

57. B. J. Casavant, A. S. Hosseini, S. R. Chemler* (2014<\/strong>), 6-Azabicyclo[3.2.1]octanes Via Copper-Catalyzed Enantioselective Alkene Carboamination, Adv. Syn. Cat<\/em>., 356<\/em>, 2697.<\/p>\n\n\n\n

56. M. T. Bovino, T. W. Liwosz, N. E. Kendel, Y. Miller, N. Tyminska, E. Zurek,* S. R. Chemler,* (2014<\/strong>) Enantioselective Copper-Catalyzed Carboetherification of Unactivated Alkenes, Angew. Chem. Int. Ed.<\/em>, 53<\/em>, 6383.<\/p>\n\n\n\n

55. B. W. Turnpenny and S. R. Chemler* (2014<\/strong>), \u201cCopper-Catalyzed Alkene Diamination: Synthesis of Chiral 2-Aminomethylindolines and Pyrrolidines,\u201d Chem. Sci<\/em>. 5<\/em>, 1786.<\/p>\n\n\n\n

54. L. Belding, S. R. Chemler, T. Dudding* (2013<\/strong>), \u201cA Computational Study of the Copper(II)-Catalyzed Enantioselective Intramolecular Aminooxygenation of Alkenes,\u201d J. Org. Chem.<\/em> 78<\/em>, 10288.<\/p>\n\n\n\n

53. T. W. Liwosz and S. R. Chemler* (2013<\/strong>), \u201cCopper-Catalyzed Oxidative Amination and Allylic Amination of Alkenes,\u201d Chemistry: A European Journal<\/em> (Wiley-Blackwell), 19, 12771.<\/p>\n\n\n\n

52. T. W. Liwosz and S. R. Chemler* (2013<\/strong>), \u201cCopper-Catalyzed Oxidative Heck<\/p>\n\n\n\n

Reactions between Alkyltrifluoroborates and Vinyl Arenes,\u201d Org. Lett. <\/em>(ACS), 15<\/em>, 3034-3037. http:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/ol401220b<\/a><\/p>\n\n\n\n

51.  M. C. Paderes, J. B. Keister,* S. R. Chemler* (2013<\/strong>), \u201cMechanistic Analysis and Optimization of the Copper-Catalyzed Enantioselective Intramolecular Alkene Aminooxygenation,\u201d 78<\/em>, 506.<\/p>\n\n\n\n

50.  S. R. Chemler* and M. T. Bovino (2013<\/strong>) \u201cCatalytic Aminohalogenation of Alkenes and Alkynes,\u201d ACS Catalysis<\/em>, 3<\/em>, 1076.<\/p>\n\n\n\n

49.  S. R. Chemler (2013<\/strong>) \u201cCopper\u2019s Contribution to Amination Catalysis,\u201d Science<\/em>, 341<\/em>, 624-626.<\/p>\n\n\n\n

48.       S. R. Chemler* and D. A. Copeland (2013<\/strong>), \u201cSynthesis of Saturated Heterocycles via Metal-Catalyzed Alkene Diamination, Aminoalkoxylation, or Dialkoxylation Reactions,\u201d Top. Heterocycl. Chem. Springer-Verlag Berlin Heidelberg J. P. Wolfe, Ed.<\/p>\n\n\n\n

47. B. W. Turnpenny, K. L. Hyman, S. R. Chemler* (2012<\/strong>), \u201cChiral Indoline Synthesis Via Enantioselective Intramolecular Copper-Catalyzed Alkene Hydroamination,\u201d Organometallics<\/em>, 31<\/em>, 7819.  https:\/\/pubs.acs.org\/doi\/10.1021\/om300744m<\/a><\/p>\n\n\n\n

46.  F. C. Sequiera, S. R. Chemler* (2012<\/strong>), \u201cStereoselective Synthesis of Morpholines Via Copper(II)-Promoted Alkene Oxyamination,\u201d Org. Lett<\/em>. 14,<\/em> 4482-4485.<\/p>\n\n\n\n

45.  S. Karyakarte, T. P. Smith, S. R. Chemler* (2012<\/strong>), \u201cStereoselective Isoxazolidine Formation via Copper-Catalyzed Alkene Aminooxygenation,\u201d J. Org. Chem<\/em>., 17, 7755-7760.<\/p>\n\n\n\n

44. Y. Miller, L. Miao, A. Hosseini, S. R. Chemler* (2012<\/strong>) \u201cCopper-Catalyzed Intramolecular Alkene Carboetherification: Synthesis of Fused-Ring and Bridged-Ring Tetrahydrofurans,\u201d J. Am. Chem. Soc<\/em>. 134<\/em>, 12149-12156.<\/p>\n\n\n\n

43. F. C. Sequeira, M. T. Bovino, A. J. Chipre, S. R. Chemler* (2012<\/strong>) \u201cMultigram Synthesis of a Chiral Substituted Indoline via Copper-Catalyzed Alkene Aminooxygenation,\u201d Synthesis,<\/em> 44<\/em>, 1481-1484 (invited special topic).<\/p>\n\n\n\n

42. M. T. Bovino and S. R. Chemler* (2012<\/strong>), \u201cCatalytic Enantioselective Alkene Aminohalogenation \/ Cyclization Involving Atom Transfer, \u201d Angew. Chem. Int. Ed.<\/em> 51<\/em>, 3923-3927.<\/p>\n\n\n\n

41.  T. W. Liwosz, S. R. Chemler* (2012<\/strong>), \u201cCopper-Catalyzed Enantioselective Intramolecular Alkene Amination \/ Intermolecular Heck-type Coupling Cascade,\u201d J. Am. Chem. Soc.<\/em> 134<\/em>, 2020-2023.<\/p>\n\n\n\n

40.  M. C. Paderes, L. Belding, B. Fanovic, T. Dudding,* J. B. Keister* and S. R. Chemler* (2012<\/strong>), \u201cEvidence for Alkene Cis-Aminocupration, an Aminooxygenation Case Study: Kinetics, EPR Spectroscopy and DFT Calculations,\u201d Chem. Eur. J<\/em>. 18<\/em>, 1711-1726.<\/p>\n\n\n\n

39.  S. R. Chemler* and B. J. Casavant (2012<\/strong>), \u201cCopper(II) 2-ethylhexanoate,\u201d contribution to The (electronic) Encyclopedia of Reagents for Organic Synthesis (e-EROS), A. B. Charette, editor.<\/p>\n\n\n\n

38.  M. C. Paderes and S. R. Chemler*<\/strong> (2011<\/strong>), \u201cStereoselective Copper-Catalyzed Intramolecular Alkene Aminooxygenation: Effect of Substrate and Ligand Structure on Selectivity,\u201d  Eur. J. Org. Chem. <\/em>Special edition, 3679-3684.<\/em><\/p>\n\n\n\n

37.   S. R. Chemler (2011)<\/strong> \u201cEvolution of copper(II) as a new alkene amination promoter and catalyst,\u201d invited review, J.<\/em> Organomet. Chem.<\/em> 696, 150-158.<\/p>\n\n\n\n

36.    S. R. Chemler (2011)<\/strong>, \u201cStereoselective nitrogen heterocycle synthesis mediated by chiral metal catalysts,\u201d Chap. 16 in Catalytic Methods in Asymmetric Synthesis: Advanced Materials, Techniques, and Applications, Wiley-VCH, M. Gruttadauria, Ed.<\/p>\n\n\n\n

35.  L. Miao, I. Haque, M. R. Manzoni, W. S. Tham and S. R. Chemler* (2010<\/strong>), \u201cDiastereo- and   <\/p>\n\n\n\n

Enantioselective Copper-Catalyzed Intramolecular Carboamination of Alkenes for the Synthesis of Hexahydro-1H<\/em>-benz[f<\/em>]indoles,\u201d Org. Lett<\/em>. 12, 4739-4741.<\/p>\n\n\n\n

34. F. C. Sequiera. B. W. Turnpenny and S. R. Chemler*<\/strong> (2010<\/strong>), \u201cCopper(II)-Promoted and Catalyzed Intermolecular Diamination of Alkenes,\u201d Angew. Chem. Int. Ed.<\/em>, 49, 6365-6368.<\/p>\n\n\n\n

33. M. Paderes and S. R. Chemler*<\/strong> (2009<\/strong>), \u201cDiastereoselective Pyrrolidine Synthesis via Copper Promoted Intramolecular Aminooxygenation of Alkenes; Formal Synthesis of (+)-Monomurine,\u201d Org. Lett. <\/em>11, 1915-1918.<\/p>\n\n\n\n

32. E. S. Sherman and S. R. Chemler* (2009<\/strong>), \u201cCopper(II)-Catalyzed Aminooxygenation and Carboamination of N-Aryl-2-allylanilines,\u201d Adv. Synth. Catal.<\/em> 351, 467-471.<\/p>\n\n\n\n

31.    S. R. Chemler, (2009<\/strong>) \u201cPhenanthroindolizidines and Phenanthroquinolizidines: Promising Alkaloids for Anti-Cancer Therapy,\u201d invited review, Current Bioactive Compounds<\/em>, 5, 2-19.<\/p>\n\n\n\n

30.    S. R. Chemler (2009)<\/strong> \u201cThe enantioselective intramolecular aminative functionalization of unactivated alkenes, dienes, allenes and alkynes for the synthesis of chiral nitrogen heterocycles,\u201d invited review, Organic and Biomolecular Chemistry, 7<\/em>, 3009-3019.<\/p>\n\n\n\n

29.    S. R. Chemler (2009<\/strong>), “Product Class Amido Derivatives of Sulfanediol,” Science of Synthesis, Vol. 40, 40.9. E. Schaumann, D. Enders, Eds.<\/p>\n\n\n\n

28.    S. R. Chemler (2009<\/strong>), “Product Class Amido Derivatives of Sulfurous Acid,” Science of Synthesis, Vol. 40, 40.10, E. Schaumann, D. Enders, Eds.<\/p>\n\n\n\n

27.    E. S. Sherman, S. R. Chemler* (2009<\/strong>), “Product Class N-Alkylsulfamic Acids and Derivatives,” Science of Synthesis, Vol. 40, 40.11, E. Schaumann, D. Enders, Eds.<\/p>\n\n\n\n

26.    S. R. Chemler (2009)<\/strong>, \u201cRoush Allylboronation,\u201d in Name Reactions for Homologations<\/em>, J. Li and E. J. Corey, Eds., pps. 613-640.<\/em><\/em><\/p>\n\n\n\n

25. J. Ni; T. Mai; S.-T. Pang, I. Haque, K. Huang, M. A. DiMaggio; S. Xie; N. S. James; D. Kasi; S. R. Chemler*<\/strong> and S. Yeh,* (2009<\/strong>) \u201cNovel Vitamin E Ether Analog Inhibits Prostate Cancer Cell Growth In Vitro and In Vivo.\u201d Clin. Cancer Res.<\/em> 15, 898-906.<\/p>\n\n\n\n

24.   P. H. Fuller, J.-W. Kim, S. R. Chemler* (2008<\/strong>) \u201cCopper catalyzed enantioselective intramolecular aminooxygenation of alkenes,\u201d J. Am. Chem. Soc<\/em>. 130, 17638-17639.<\/p>\n\n\n\n

23.  W. Zeng., S. R. Chemler* (2008<\/strong>) \u201cTotal Synthesis of (S)-(+)-Tylophorine Via Enantioselective Intramolecular Alkene Carboamination.\u201d J. Org. Chem.<\/em> 73, 6045-6047.<\/p>\n\n\n\n

22.    S. R. Chemler (2008<\/strong>) \u201cIsopropenyllithium,\u201d contribution to The Encyclopedia of Reagents for Organic Synthesis (EROS), L. Paquette, editor.<\/p>\n\n\n\n

21.   P. H. Fuller and S. R. Chemler* (2007<\/strong>) \u201cCopper(II) Carboxylate Promoted Intramolecular<\/p>\n\n\n\n

    Carboamination of Alkenes for the Synthesis of Polycyclic Lactams,\u201d Org. Lett<\/em>. 9, 5477-5480.**<\/p>\n\n\n\n

20.   W. Zeng and S. R. Chemler* (2007<\/strong>) \u201cCopper(II)-Catalyzed Enantioselective Intramolecular Carboamination of Alkenes,\u201d J. Am. Chem. Soc. <\/em>129, 12948-12949.**<\/p>\n\n\n\n

19.   T. P. Zabawa, S. R. Chemler* (2007)<\/strong> \u201cCopper(II) Carboxylate Promoted Intramolecular Diamination of Unactivated Alkenes for the Synthesis of Cyclic Vicinal Diamines: Diastereoselectivity and Expanded Substrate Scope\u201d Org. Lett.<\/em> 9. 2035-2038.<\/p>\n\n\n\n

18.   E. S. Sherman; P. H. Fuller; D. Kasi; S. R. Chemler,* (2007<\/strong>), \u201cPyrrolidine and Piperidine Formation Via Copper(II) Carboxylate Promoted Intramolecular Carboamination of Unactivated Olefins: Diastereoselectivity and Mechanism,\u201d J. Org. Chem.<\/em> 72, 3896-3905.<\/p>\n\n\n\n

17.   E. Cheng, J. Ni, Y. Yin, C. C. Lin, P. Chang, N. S. James, S. R. Chemler, S. Yeh* (2007<\/strong>), \u201calpha-Vitamin E Derivative, RRR-alpha-Tocopheryloxybutyric Acid Inhibits the Proliferation of Prostate Cancer Cells,\u201d Asian J. Andrology<\/em>, 9<\/em>. 31.<\/p>\n\n\n\n

16.    S. R. Chemler* and P. H. Fuller (2007<\/strong>) \u201cHeterocycle Synthesis by Copper Facilitated Additions of Amines to Alkenes, Alkynes and Arenes,\u201d invited review, Chemical Society Reviews<\/em>, 36<\/em>, 1153-1160.<\/p>\n\n\n\n

15.   S. R. Chemler and T. P. Zabawa (2006<\/strong>) \u201cThree Carbon-Heteroatom Bonds: Alpha-Heteroatom Substituted Alkanoic Acids and their Ester Derivatives,\u201d Science of Synthesis, Vol. 20a, E. Jacobsen, Ed. Section 20.2.8, \u201cProduct Subclass 8: 2-Heteroatom-Substituted Alkanoic Acids,\u201d 483-505.<\/p>\n\n\n\n

14.    S. R. Chemler and T. P. Zabawa (2006<\/strong>) \u201cThree Carbon-Heteroatom Bonds: Alpha-Heteroatom Substituted Alkanoic Acids and their Ester Derivatives,\u201d Science of Synthesis, Vol. 20b, E. Jacobsen, Ed. Section 20.5.11, \u201cProduct Subclass 11: 2-Heteroatom-Substituted Alkanoic Acid Esters,\u201d 1203-1242.<\/p>\n\n\n\n

13.   T. P. Zabawa, D. Kasi, S. R. Chemler,*  (2005<\/strong>) \u201cCopper(II) Acetate Promoted Intramolecular Diamination of Unactivated Olefins,\u201d J. Am. Chem. Soc., 127, <\/em>11250-11251.<\/em><\/p>\n\n\n\n

12.   Y. Wu, K. Zu, J. Ni, S. Yeh, D. Kasi, N. S. James, S. R. Chemler and C. Ip* (2004<\/strong>).  \u201cCellular and Molecular Effects of alpha-Tocopheryloxybutyrate: Lessons for the Design of Vitamin E Analog for Cancer Prevention\u201d Anticancer Research, 24<\/em>, 3795-3802.<\/p>\n\n\n\n

11.   M. R. Manzoni, T. P. Zabawa, D. Kasi and S. R. Chemler*<\/strong> (2004<\/strong>). \u201cPalladium(II) Catalyzed Intramolecular Aminobromination and Aminochlorination of Olefins,\u201d Organometallics<\/em>, 5618-5621.<\/p>\n\n\n\n

10.   E. S. Sherman, S. R. Chemler,* T. B. Tan and O. Gerlits (2004<\/strong>). \u201cCopper(II) Acetate Promoted Oxidative Cyclization of Arylsulfonyl-o-allylanilines,\u201d Org. Lett.<\/em> 10<\/em>, 1573-1575.<\/p>\n\n\n\n

Prior to UB (PhD and Postdoc)<\/p>\n\n\n\n

9.     S. R. Chemler, W. R. Roush* (2003<\/strong>). \u201cStereochemistry of the Allylation and Crotylation Reactions of alpha-Methyl-beta-Hydroxy Aldehydes with Allyl- and Crotyltrifluorosilanes.  Synthesis of Anti, Anti-Dipropionate Stereotriads and Stereodivergent Pathways for the Reactions of 2,3-Anti and 2,3-Syn alpha-Methyl-beta-Hydroxy Aldehydes,\u201d J. Org. Chem<\/em>. 68<\/em>, 1319-1333.<\/p>\n\n\n\n

8.      S. R. Chemler, D. Trauner and S. J. Danishefsky* (2001<\/strong>) \u201cThe B<\/em>-Alkyl Suzuki-Miyaura Cross-Coupling Reaction: Development, Mechanistic Study and Applications in Natural Product Synthesis,\u201d Angew. Chem. Int. Ed., 40<\/em>, 4544-4568.<\/p>\n\n\n\n

7.      S. R. Chemler and W. R. Roush (2000<\/strong>) \u201cRecent Applications of the Allylation Reaction to the Synthesis of Natural Products\u201d Chap. 11 in Modern Carbonyl Chemistry<\/em>, J. Otera, Ed., Wiley-VCH: Weinheim.<\/p>\n\n\n\n

6.     S. R. Chemler, U. Iserloh and S. J. Danishefsky* (2001<\/strong>). \u201cToward an Enantioselective Synthesis of Phomactin A: Construction of the Oxadecalin Core via a Highly Stereoselective Diels-Alder Reaction,\u201d Org. Lett<\/em>. 3<\/em>, 2949-2951.<\/p>\n\n\n\n

5.     S. R. Chemler and S. J. Danishefsky* (2000<\/strong>). \u201cTransannular Macrocyclization via Intramolecular B<\/em>-Alkyl Suzuki Reaction,\u201d Org. Lett. 2<\/em>, 2695-2698.<\/p>\n\n\n\n

4.     S. R. Chemler, D. S. Coffey and W. R. Roush* (1999<\/strong>). \u201cAn Improved Synthesis of the (E,Z<\/em>)-Dienoate Precursor of (+)-Damavaricin D Via a Vinylogous Horner-Wadsworth-Emmons Reaction,\u201d Tetrahedron Lett.<\/em> 40<\/em>, 1.<\/p>\n\n\n\n

3.     S. R. Chemler and W. R. Roush* (1999<\/strong>). \u201cStereochemically Divergent Pathways for the Allylation and Crotylation Reactions of Anti- and Syn-beta-Hydroxy-alpha-Methyl Aldehydes with Allyl- and Crotyltrifluorosilanes,\u201d Tetrahedron Lett., 40<\/em>, 4643-4647.<\/p>\n\n\n\n

2.     K. A. Scheidt, H. Chen, B. C. Follows, S. R. Chemler, D. S. Coffey and W. R. Roush* (1998<\/strong>).  \u201cTris(dimethylamino)sulfonium Difluorotrimethylsilicate, a Mild Reagent for the Removal of Silicon,\u201d J. Org. Chem. 19<\/em>, 6436-6437.<\/p>\n\n\n\n

1.     S. R. Chemler and W. R. Roush* (1998<\/strong>). \u201cConcerning the Synthesis of the Elusive Anti,Anti-Dipropionate Stereotriad via the Crotylation of alpha-Methyl-beta-Hydroxy Aldehydes with (Z<\/em>)-Crotyltrifluorosilane.  Application to the Synthesis of the C(7)-C(16) Segment of Zincophorin,\u201d J. Org. Chem. 63<\/em>, 3800-3801.<\/p>\n","protected":false},"excerpt":{"rendered":"

84. J. J. Kennedy-Ellis, A. D. Kelleher, J. A. Sayeed, A. S. Burde and S. R. Chemler,* (2024) \u201cEnantioenriched allylesters via a copper-catalyzed diene carboesterification with alkyltrifluoroborates and carboxylic acids,\u201d … Continue reading Publications<\/span><\/a><\/p>\n","protected":false},"author":517,"featured_media":0,"parent":0,"menu_order":0,"comment_status":"closed","ping_status":"closed","template":"","meta":{"footnotes":""},"class_list":["post-26","page","type-page","status-publish","hentry"],"_links":{"self":[{"href":"https:\/\/ubwp.buffalo.edu\/chemlerlab\/wp-json\/wp\/v2\/pages\/26","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/ubwp.buffalo.edu\/chemlerlab\/wp-json\/wp\/v2\/pages"}],"about":[{"href":"https:\/\/ubwp.buffalo.edu\/chemlerlab\/wp-json\/wp\/v2\/types\/page"}],"author":[{"embeddable":true,"href":"https:\/\/ubwp.buffalo.edu\/chemlerlab\/wp-json\/wp\/v2\/users\/517"}],"replies":[{"embeddable":true,"href":"https:\/\/ubwp.buffalo.edu\/chemlerlab\/wp-json\/wp\/v2\/comments?post=26"}],"version-history":[{"count":6,"href":"https:\/\/ubwp.buffalo.edu\/chemlerlab\/wp-json\/wp\/v2\/pages\/26\/revisions"}],"predecessor-version":[{"id":283,"href":"https:\/\/ubwp.buffalo.edu\/chemlerlab\/wp-json\/wp\/v2\/pages\/26\/revisions\/283"}],"wp:attachment":[{"href":"https:\/\/ubwp.buffalo.edu\/chemlerlab\/wp-json\/wp\/v2\/media?parent=26"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}